Abstract
This article presents a technical investigation into a set of four artist- and date-unknown paintings of Chinese Taoist priests, which aimed to reveal their fiber source, painting technique, starch-based adhesive, and pigment use for the purpose of future conservation treatment. By using an integrated approach (Herzberg staining, cross-sectioning, starch grain analysis, X-ray fluorescence, Raman spectroscopy, and X-ray diffraction), it turned out clear that (1) bamboo was the primary (if not the only) fiber source; (2) multiple layers were utilized in combination with simply outlining and filling, while paintings were in preparation; (3) wheat flour, a starch-based adhesive, was used to hold together the painting paper and the paper supports underneath; and (4) vermilion, emerald green, synthetic ultramarine blue, orpiment, lead white, and carbon black were used to produce the six main colors on the paintings. The discoveries of emerald green and synthetized ultramarine blue placed the earliest possible manufacturing dates of these paintings around the 1830s.











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References
Bell IM, Clark RJH, Gibbs PJ (1997) Raman spectroscopic library of natural and synthetic pigments (pre-≈1850 AD). Spectrochim Acta A Mol Biomol Spectrosc 53(12):2159–2179
Bell S, Bourguignon E, Denns A, Fields J, McGarvey J, Seddon K (2000) Identification of dyes on ancient Chinese paper samples using the subtracted shifted Raman spectroscopy method. Anal Chem 72(1):234–239
Burgio L, Clark RJH (2000) Comparative pigment analysis of six modern Egyptian papyri and an authentic one of the 13th century BC by Raman microscopy and other techniques. J Raman Spectrosc 31(5):395–401
Burgio L, Clark R, Gibbs PJ (1999) Pigment identification studies in situ of Javanese, Thai, Korean, Chinese and Uighur manuscripts by Raman microscopy. J Raman Spectrosc 30(3):181–184
Burgio L, Clark RJH, Firth S (2001) Raman spectroscopy as a means for the identification of plattnerite (PbO2), of lead pigments and of their degradation products. Analyst 126(2):222–227
Chen T-H, Chen C-F (2014) Investigation of pigments on the Xi Qing Xu Jian mirror cases. J Nat Taiwan Mus 67(1):13–29 (in Chinese)
Cheng X, Xia Y, Ma Y, Lei Y (2007) Three fabricated pigments (Han purple, indigo and emerald green) in ancient Chinese artifacts studied by Raman microscopy, energy-dispersive X-ray spectrometry and polarized light microscopy. J Raman Spectrosc 38(10):1274–1279
Clark FC (1920) Paper testing methods: microscopical, chemical and physical processes described with an account of the apparatus employed. TAPPI Publishing Corporation, New York
Collings T, Milner D (1978) The identification of oriental paper-making fibers (I). Paper Conservator 3(1):51–79
Collings T, Milner D (1979) The identification of non-wood paper-making fibers (Part II). Paper Conservator 4(1):10–19
Collings T, Milner D (1982) The identification of non-wood paper-making fibers (Part III). Paper Conservator 7(1):24–27
Correia AM, Clark RJH, Ribeiro MIM, Duarte MLTS (2007) Pigment study by Raman microscopy of 23 paintings by the Portuguese artist Henrique Pousão (1859–1884). J Raman Spectrosc 38(11):1390–1405
Fitzhugh EW (1997) Artists’ pigments: a handbook of their history and characteristics (volume III). National Gallery of Art, Washington D.C
Galt HM (1900) The microscopy of the more commonly occuring starches. Bailiere, Tinall & Cox, London
Gong D, Xi S, Tang J (1997) Conservation of paper-based materials. Southeast Cult 1997(4):131–136 (in Chinese)
Huang J-F (2006) A technical examination of 7 Thai manuscripts in the 18th, 19th, and 20th centuries. Association of North American Graduate Programs in the Conservation of Cultural Property. https://pacer.ischool.utexas.edu/handle/2081/3222
Isenberg IH (1967) Pulp and paper microscopy (the third edition). The Institute of Paper Chemistry. Appleton, Wisconsin
Li Z, Wang L, Ma Q, Mei J (2014) A scientific study of the pigments in the wall paintings at Jokhang Monastery in Lhasa, Tibet, China. Herit Sci 2(1):21
Ma Z, Yang X, Li Q, Wan Z, Li M, Ge Q (2012) Stone knives function: simulation experiment vis starch grain analysis. Quat Sci 32(2):247–255 (in Chinese)
Marx A (2002) Indigo, smalt, ultramarine-a change of blue paints in traditional Ethiopian church paintings in the 19th century sets a benchmark for dating. Paper presented in the XIVth International Conference of Ethiopian Studies. Addis University Press, Addis Ababa
Mazzeo R, Cam D, Chiavari G, Fabbri D, Ling H, Prati S (2004) Analytical study of traditional decorative materials and techniques used in Ming Dynasty wooden architecture. The case of the Drum Tower in Xi’an, P.R. of China. J Cult Herit 5(3):273–283
Na N, Ouyang Q, Qiao Y, Ouyang J, Wang Y (2004) Rapid and non-destructive identification of calligraphies by Fourier transform infrared spectroscopy and Fourier transform Raman spectroscopy. Spectrosc Spectr Anal 24(11):1327–1330 (in Chinese)
National Research Institute of Cultural Heritage of South Korea (2012) Conservation of papers and textiles. National Research Institute of Cultural Heritage of South Korea, Seoul, South Korea
Osticioli I, Mendes NF, Necin A, Gil EP, Becucci M, Castellucci E (2009) Analysis of natural and artificial ultramarine blue pigments using laser induced breakdown and pulsed Raman spectroscopy, statistical analysis and light microscopy. Spectrochim Acta A Mol Biomol Spectrosc 73(3):525–531
Paltakari J (ed) (2009) Pigment coating & surface sizing of paper. The papermaking science & technology series. The Finnish Paper Engineers’ Association & Paper ja Puu Oy, Jyväskylä, Finland
Pan J (2002) The four great inventions of ancient China: their origin, development, spread and influence in the world. University of Science And Technology of China Press, Hefei (in Chinese)
Rosi F, Miliani C, Borgia I, Brunetti B, Sgamellotti A (2004) Identification of nineteenth century blue and green pigments by in situ x-ray fluorescence and micro-Raman spectroscopy. J Raman Spectrosc 35(8–9):610–615
Roy A (1997) Artists’ pigments: a handbook of their history and characteristics (volume II). National Gallery of Art, Washington D.C
Shen A, Wang X, Xie W, Shen J, Li H, Liu Z, Hu J (2006) Pigment identification of colored drawings from Wuying Hall of the Imperial Palace by micro-Raman spectroscopy and energy dispersive X-ray spectroscopy. J Raman Spectrosc 37(1–3):230–234
Shi J, Li T (2013) Technical investigation of 15th and 19th century Chinese paper currencies: fiber use and pigment identification. J Raman Spectrosc 44(6):892–898
Shi J, Mu Y, Zhang Y, Luo W, Wang R, Fang X (2010) The nondestructive identification of printing pigments in bank notes issued by Yantai Xigongshun, the Republic of China. China Print Packag Study 2(z1):461–463 (in Chinese)
Taylor T (2007) Oriental papermaking fibres. http://cultural-conservation.unimelb.edu.au/PapermakingFibres/. Accessed March 15, 2010
Tsai F, van der Reyden D (1997) Analysis of modern Chinese paper and treatment of a Chinese woodblock print. Paper Conservator 21(1):48–62
van der Reyden D (1993) Pigment-coated papers I: history and technology. Paper presented in the 10th Triennial Meeting, ICOM, Washington D.C.
Wang B (1982) History of Chinese paintings. Shanghai People’s Fine Arts Publishing House, Shanghai (in Chinese)
Wang J (1996) Study on the blue pigments noticed on paintings in the Mogao Caves, Dunhuang. Archaeology 1996(3):74–80 (in Chinese)
Wang J (2000) Study on synthetic ultramarine blue found in the Mogao Caves. Dunhuang Res 2000(1):76–81 (in Chinese)
Wang J (2009) A search for the provenance of natural ultramarine blue as a blue pigment in ancient Chinese art. Wenbo 2009(6):396–402 (in Chinese)
Wang H, Cheng A, Ma Q, Wang Z, Wang C (2014) Identifying the pigments of a Ming dynasty water-and-land painting. Dunhuang Res 2014(5):119–124 (in Chinese)
Wehling B, Vandenabeele P, Moens L, Klockenkämper R, Av B, Hooydonk GV, Reu MD (1999) Investigation of pigments in medieval manuscripts by micro Raman spectroscopy and total reflection X-ray fluorescence spectrometry. Microchim Acta 130(4):253–260
Yin T (2000) Ancient Chinese ink and the invention of printing technology. J Guyuan Teach Coll (Social Sciences) 21(4):67–69 (in Chinese)
Acknowledgments
This research would not have been possible without financial support by the National Key Technology R&D Program (No. 2014BAH07F01), Beijing Municipal Science & Technology Commission (No. 2010B034), and Beijing Institute of Graphic Communication Projects (Nos. E-a-2013-21 and E-b-2015-35). Special thanks go to Senior Engineer Shifeng Liu (Horiba Jobin Yvon, Beijing) and Mrs. Qiuju He (Capital Museum, Beijing) for their sincere help in Raman and X-ray fluorescence analyses. The authors would also like to thank the two anonymous reviewers for offering their insightful comments, which improves the clarity, consistency, and coherence of the paper’s arguments.
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Li, T., Ji, J., Zhou, Z. et al. A multi-analytical approach to investigate date-unknown paintings of Chinese Taoist priests. Archaeol Anthropol Sci 9, 395–404 (2017). https://doi.org/10.1007/s12520-015-0293-9
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DOI: https://doi.org/10.1007/s12520-015-0293-9